A quantum optics approach to photoinduced electron transfer in cavities

نویسندگان

چکیده

We study a simple model for photoinduced electron transfer reactions the case of many donor–acceptor pairs that are collectively and homogeneously coupled to photon mode cavity. describe both coherent dissipative collective effects resulting from this coupling within framework quantum optics Lindblad master equation. introduce method derive an effective rate equation by adiabatically eliminating donor acceptor states cavity mode. The is valid weak strong describes electronic through cavity-coupled bright uncoupled dark states. analytic expression instantaneous depends non-trivially on time-varying number in ground state. find under proper resonance conditions, presence incoherent drive, reaction rates can be enhanced This enhancement persists, even largest, light–matter regime. discuss how effect relevant realistic experiments.

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ژورنال

عنوان ژورنال: Journal of Chemical Physics

سال: 2021

ISSN: ['1520-9032', '1089-7690', '0021-9606']

DOI: https://doi.org/10.1063/5.0037412